定语从句 the buses,__were already full,were surrounded by an angry crowd.请问用most of that 为什么用that不行?

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定语从句 the buses,__were already full,were surrounded by an angry crowd.
请问用most of that 为什么用that不行?

你好
most of which 比较好!
that 一般都是单独用 没有见过组合着用的! 而 which 可以